04-05 Chemical Bonding and Materials, Set A Answer Key To print: Ctrl + P, paper A4, margins Default.
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04-05

Chemical Bonding and Materials

Set AAnswer key
A

From the lesson

8 marks
1

Bionic bonding[1]

Magnesium is a metal and oxygen is a non-metal. Magnesium loses 2 electrons and oxygen gains them, so ions form and attract each other.

2

Bgraphite[1]

Each carbon atom in graphite uses only 3 of its 4 outer electrons, so one electron per atom is free to move.

3

BEach carbon atom is bonded to four others by strong covalent bonds.[1]

A large amount of energy is needed to break the many strong covalent bonds in the giant network.

4

B2[1]

Each oxygen atom has 6 outer electrons and shares 2 of them. This makes a double bond, which is two shared pairs.

5
(a)

A sodium atom loses 1 electron to form a sodium ion, Na+. [1]

A chlorine atom gains 1 electron to form a chloride ion, Cl−. [1]

(b)

Ionic bond. [1]

It is the electrostatic attraction between the oppositely charged ions. [1]

B

Practice

28 marks
6

Bphosphorus and oxygen[1]

Covalent bonds form between non-metals. Phosphorus and oxygen are both non-metals. The other pairs are a metal and a non-metal, which form ionic bonds.

7

Aelectrostatic forces of attraction between positive metal ions surrounded by a ‘sea of delocalised electrons’[1]

Metal atoms lose their outer electrons to form positive ions. The attraction between oppositely charged particles is electrostatic.

8

ACopper has a ‘sea’ of delocalised electrons.[1]

The delocalised electrons are mobile charge carriers. The positive ions stay in fixed positions.

9

DCa3(PO4)2[1]

Calcium forms Ca2+ and phosphate is PO43−. Three Ca2+ (+6) balance two PO43− (−6).

10

Cgiant ionic structure, because it has free-moving ions[1]

The ions are fixed in the solid but move freely when dissolved.

AA metal conducts as a solid, and pure water is a poor conductor.BA metal conducts as a solid.DPure water is a poor conductor. The ions in the solution carry the current.
11

Bair, tungsten, sodium bromide[1]

Tungsten is a metallic element, sodium bromide is an ionic compound and air is a gaseous mixture. The order in the list does not matter.

12

DD[1]

In D, atoms of two different elements join to form particles of a new compound, so a new substance is made.

13

CIn an alloy there is attraction between positive ions and a ‘sea of delocalised electrons’.[1]

An alloy still has metallic bonding. It can contain a non-metal, as steel contains carbon, and it is a mixture, so brass has no chemical formula.

14
(a)(i)

Sodium sulfate [1]

(ii)

Graphite [1]

(iii)

Sulfur dioxide and sodium sulfate [1]

Both contain sulfur and oxygen.

(iv)

Dry ice [1]

(v)

Graphite [1]

(vi)

Any one: dry ice, CO2 or sulfur dioxide, SO2 or sodium sulfate, Na2SO4. [1]

(b)

Correct number of electrons: a nitrogen atom with 3 shared pairs and 1 lone pair, and each hydrogen atom with 1 shared pair. [1]

Correct number of atoms: one nitrogen atom bonded to three hydrogen atoms. [1]

15
(a)

A giant metallic structure, a lattice of positive ions [1]

in a sea of delocalised electrons. [1]

(b)(i)

Sc2(SO4)3 [1]

Sc2O3 shows that scandium forms Sc3+ and sulfate is SO42−.

(ii)

Sc(OH)3 [1]

16
(a)

The correct ratio of two Li+ ions to one O2− ion. [1]

Each ion shown with its charge: Li+ with no outer electrons and O2− with 8 outer electrons, in square brackets. [1]

(b)

Li2O: solid [1]

CH4: gas [1]

(c)(i)

Li2O has a giant ionic lattice. [1]

As a solid, the ions are held in fixed positions and cannot move freely to conduct electricity. [1]

(ii)

CH4 consists of simple molecules. [1]

The weak intermolecular forces of attraction need little energy to overcome, so the melting and boiling points are low. [1]