11 Qualitative Analysis, Set A To print: Ctrl + P, paper A4, margins Default.
Learners' AlleyDesigned by Khow Willard
11

Qualitative Analysis

Set AFoundations
Name
Time 45 minutes
Total 18 marks

Use a copy of the Periodic Table where you need one.

A

From the lesson

7 marks
1

Which cation gives a white precipitate with aqueous sodium hydroxide that is insoluble in excess?

Aaluminium, Al3+
Bcalcium, Ca2+
Czinc, Zn2+
Dammonium, NH4+
Answer [1]

Source: Learners' Alley, Qualitative Analysis slides

2

A solution is acidified with dilute nitric acid, then aqueous silver nitrate is added. A yellow precipitate forms. Which ion is present?

Achloride, Cl−
Biodide, I−
Csulfate, SO42−
Dcarbonate, CO32−
Answer [1]

Source: Learners' Alley, Qualitative Analysis slides

3

A pungent gas turns damp blue litmus paper red, then bleaches it. What is the gas?

Aammonia
Bcarbon dioxide
Cchlorine
Dsulfur dioxide
Answer [1]

Source: Learners' Alley, Qualitative Analysis slides

4

Answer these questions about qualitative analysis.

(a)
State the result when aqueous ammonia is added to a solution of iron(III) ions until in excess.
[1]
(b)
Describe the test for sulfate ions.
[1]
(c)
Describe the test for hydrogen.
[1]
(d)
Name the reagent used to tell aluminium ions from zinc ions.
[1]

Source: Learners' Alley, Qualitative Analysis slides

B

Practice

11 marks
5

When sulfur is burned, sulfur dioxide is produced. How can the identity of sulfur dioxide be confirmed?

testobservation
Ainsert a glowing splint into the gasthe glowing splint rekindles
Buse a piece of damp blue litmus paperblue litmus paper turns red and is then bleached
Cuse a piece of damp red litmus paperred litmus paper turns blue and is then bleached
Duse a piece of filter paper soaked with acidified potassium manganate(VII)purple potassium manganate(VII) turns colourless
Answer [1]

Source: 2023 GESS Sec 3 End-of-Year P1 Q34

6

Separate tests were performed on an unknown solution. The results are shown in the table. What is the unknown solution?

testobservation
add aqueous sodium hydroxidegreen precipitate forms and is insoluble in excess sodium hydroxide
add nitric acidno observable change
add aqueous sodium hydroxide, aluminium foil and warmpungent gas evolved which turned moist red litmus paper blue
Aammonium nitrate
Biron(II) carbonate
Ciron(II) nitrate
Diron(III) sulfate
Answer [1]

Source: 2023 GESS Sec 3 End-of-Year P1 Q35

7

An excess of aqueous sodium hydroxide is added to an aqueous solution of salt X and boiled. Ammonia gas is only given off after aluminium foil is added to the hot solution. What could X be?

Aammonium chloride
Bammonium iodide
Csodium chloride
Dsodium nitrate
Answer [1]

Source: 2024 CHS Sec 3 End-of-Year Section A Q27

8

There are two unlabelled test tubes. One contains aqueous ammonium nitrate and the other contains aqueous sodium nitrate. Which test could identify the solutions?

Aadd aqueous ammonia and warm
Badd aqueous sodium hydroxide and warm
Cadd aqueous sodium hydroxide, aluminium foil and warm
Dadd dilute hydrochloric acid and warm
Answer [1]

Source: 2020 SJI Year 3 End-of-Year P1 Q20

9

Three substances were added separately to aqueous potassium sulfate and to aqueous potassium carbonate.
1  aqueous ammonia
2  barium nitrate solution
3  dilute hydrochloric acid
Which substance(s) would give different observations with the two solutions?

A1 only
B3 only
C1 and 2
D2 and 3
Answer [1]

Source: 2020 SJI Year 3 End-of-Year P1 Q19

10

A solution of compound Z reacts with sodium hydroxide solution to form a white precipitate that is insoluble in excess sodium hydroxide solution. Aluminium powder is then added. The mixture is heated and a gas that turns damp red litmus paper blue is given off. What could Z be?

Aaluminium chloride
Bammonium chloride
Ccalcium nitrate
Dzinc nitrate
Answer [1]

Source: 2024 CHIJ Prelim P1 Q18

11

Aqueous ammonia is commonly used to identify cations which are present in salt solutions.

(a)
Describe how aqueous ammonia can be used to identify iron(II) ions.
[1]
(b)
Write an ionic equation, with state symbols, for the reaction in (a).
[2]

Source: 2021 SJI Prelim P2 A2(b)

12

Describe what you see when:

(a)
a few drops of aqueous ammonia are added to an aqueous solution containing copper(II) ions.
[1]
(b)
excess aqueous ammonia is added to an aqueous solution containing copper(II) ions.
[1]

Source: 2025 TKGS Prelim P2 Q(c)