11 Qualitative Analysis, Set B Answer Key To print: Ctrl + P, paper A4, margins Default.
Learners' AlleyDesigned by Khow Willard
11

Qualitative Analysis

Set BAnswer key
A

Multiple choice

5 marks
1

DKNO3, NaOH, Na2SO4[1]

A gives a red-brown precipitate of iron(III) hydroxide, B gives a white precipitate of barium sulfate, and C is blue because of the copper(II) ions.

2

BAmmonia gas is produced.[1]

The acid reacts with the carbonate to give carbon dioxide, which is acidic. Ammonia is given off by ammonium salts with an alkali, not with an acid.

3

Abarium nitrate solution[1]

Barium nitrate gives a white precipitate of barium sulfate with sulfuric acid only. The other reagents give the same result with both acids.

4

Dsodium nitrate[1]

Warming with sodium hydroxide drives off the ammonium ions as ammonia. Barium sulfate is filtered off, leaving sodium and nitrate ions in the filtrate.

5

Czinc carbonate[1]

The gas is carbon dioxide, so the solid is a carbonate. The hydroxide dissolves in excess aqueous ammonia, so the cation is zinc. The chloride in test 1 comes from the hydrochloric acid.

B

Structured questions

15 marks
6
(a)

A: calcium carbonate, CaCO3 [1]

C: calcium chloride, CaCl2 [1]

D: carbon dioxide, CO2 [1]

E: calcium hydroxide, Ca(OH)2 [1]

(b)

Ca2+(aq) + 2OH−(aq) → Ca(OH)2(s) [1]

(c)

Aqueous barium nitrate: no observable change. [1]

Aqueous silver nitrate: a white precipitate forms. [1]

7
(a)

T: iron(II) chloride [1]

U: carbon dioxide [1]

V: iron(II) hydroxide [1]

W: silver chloride [1]

(b)

Iron(II), carbonate and nitrate ions (all three needed). Chloride is not accepted, as it could have come from the hydrochloric acid. [1]

(c)

Any one, e.g. CO2 + Ca(OH)2 → CaCO3 + H2O or Fe2+(aq) + 2OH−(aq) → Fe(OH)2(s) [1]

8

Calcium hydroxide reacts with ammonium-based fertilisers to form ammonia gas, which escapes into the atmosphere. [1]

This results in the loss of nitrogen from the fertiliser, which plants need for growth. [1]