08 The Periodic Table and Periodicity, Set B To print: Ctrl + P, paper A4, margins Default.
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08

The Periodic Table and Periodicity

Set BCompetition Practice
Name
Time 45 minutes
Total 24 marks
A

Competition questions

24 marks
1

The table gives the successive ionisation energies, in kJ mol−1, of five elements in Period 3.

elementIE1IE2IE3IE4IE5
V78715773231435616091
W738145177331054013630
X12512297382251586540
Y49645626912954313353
Z578181727451157514830

Based on this information, which of the following statements is false?

AW is an alkaline earth metal.
BY is sodium.
CZ forms the largest cation.
DX has the smallest radius.
Answer [1]

Source: 2023 SJChO P1 Q38

2

The first eight ionisation energies of an element Q in kJ mol−1 are 966, 1950, 2730, 4850, 6020, 12 300, 15 400 and 18 900. Which of the following statements about element Q is correct?

AIt can form a basic oxide.
BIt can form a chloride with the formula QCl5.
CIt has an even number of protons in its atom.
DIt can form a chloride that is trigonal planar in shape.
Answer [1]

Source: 2021 SAJC J2 Prelim P1 Q2

3

Which statement best explains why the second ionisation energy of sodium is higher than that of magnesium?

AMagnesium has more protons than sodium.
BSodium has a complete octet but magnesium does not.
CThe ionic radius of Na+ is larger than that of Mg+.
DThe electron to be removed from sodium is closer to the nucleus.
Answer [1]

2018 RVHS J1 Common Test P1 Q4

4

Rubidium and bromine form ions that are isoelectronic. Which statements are correct?

1 The ionic radius of rubidium is smaller than its atomic radius.
2 The ionic radius of bromine is larger than its atomic radius.
3 The ionic radius of bromine is smaller than that of rubidium.

A1, 2 and 3
B1 and 2 only
C1 and 3 only
D2 and 3 only
Answer [1]

2022 NJC J2 Prelim P1 Q6

5

Which statement about the Period 3 elements and their oxides is false?

AThe pH of the oxides in water decreases across the period.
BThe melting points of the elements decrease across the period.
CThe covalent character of the oxides increases across the period.
DThe maximum oxidation state of the elements increases across the period.
Answer [1]

2020 SAJC J2 Prelim P1 Q14

6

P, Q, R and S are elements in Period 3.

The oxide of P dissolves in water to give a solution with pH less than 7.
The oxide of Q has a giant covalent structure.
Element R is a metal which floats on water.
Element S is used to fill light bulbs.

Which arranges the four elements in order of increasing proton number?

AR, Q, P, S
BR, P, Q, S
CS, Q, P, R
DS, P, Q, R
Answer [1]

2024 Woodlands O Prelim P1 Q23

7

What is the order of the pH of the solutions formed when these oxides are added to water?

lowest pHhighest pH
ASO3SiO2MgONa2O
BNa2OMgOSiO2SO3
CMgOSiO2SO3Na2O
DSO3Na2OMgOSiO2
Arow A
Brow B
Crow C
Drow D
Answer [1]

2019 HCI J2 Prelim P1 Q27

8

Which statement does not describe the chemical properties of Period 3 compounds?

ASiO2 is formed from the hydrolysis of SiCl4.
BAl2O3 is soluble in both acid and base.
CEqual amounts of Na2O and SO3 can be mixed in water to give a neutral solution.
DThe acidity of the Period 3 chlorides in water decreases from NaCl to PCl5.
Answer [1]

2019 NJC J2 Prelim P1 Q15

9

The oxides of four Period 3 elements W, X, Y and Z behave as follows.

The oxide of W is insoluble in water and in dilute HCl, but dissolves in concentrated NaOH.
The oxide of X is insoluble in water but dissolves in both dilute HCl and dilute NaOH.
The oxide of Y dissolves in dilute NaOH at room temperature.
The oxide of Z dissolves in water to form a solution of pH 13.

What is the order of increasing atomic number?

AZ, X, W, Y
BY, W, X, Z
CW, X, Y, Z
DZ, Y, W, X
Answer [1]

2019 NYJC J2 MYE P1-P3 Q16

10

X, Y and Z are in Period 3. The oxide of X gives a solution of pH less than 7. The oxide of Y reacts with both strong acids and strong alkalis. The oxide of Z gives a strongly alkaline solution. What is the order of increasing atomic radius?

AX < Y < Z
BX < Z < Y
CY < Z < X
DZ < Y < X
Answer [1]

2019 SAJC J2 Prelim P1 Q19

11

Four elements with atomic numbers 11 to 17 have these properties.

The chloride of E dissolves in water and turns moist blue litmus red.
The oxide of F is amphoteric.
G has the lowest electronegativity of the four.
H has the smallest atomic radius.

What is the order of increasing atomic number?

AF, G, H, E
BF, G, E, H
CG, F, E, H
DG, F, H, E
Answer [1]

2019 CJC J2 Prelim P1 Q14

12

Element X is in Period 3. Three of these statements about X or its compounds are correct and one does not fit. Which statement does not fit?

AX is a solid at room temperature which conducts electricity.
BThe chloride of X reacts with water to give an acidic solution.
CThe oxide of X reacts with water to give an acidic solution.
DAdding NaOH(aq) to the solution from XCl3 and water gives a white precipitate, soluble in excess NaOH(aq).
Answer [1]

2021 CJC J2 Prelim P1 Q9

13

Element G is one of the first five elements in Period 3. Three of these statements about G or its compounds are correct and one is false. Which statement does not fit?

AThe oxide of G dissolves in excess dilute NaOH(aq).
BG has only one oxidation number in its chloride, which is not a solid at room temperature.
CThe oxide of G has a very high melting point.
DThe chloride of G reacts with water to give an acidic solution of pH 2.
Answer [1]

2021 TMJC J2 Prelim P1 Q6

14

Element Z is in Period 3. Its oxide has a giant molecular structure and its chloride is a simple molecule. Which statements are correct?

1 Element Z is a solid at room temperature.
2 The oxide of Z reacts with water to give an acidic solution.
3 Z forms two chlorides with different oxidation states.

A1 only
B1 and 3 only
C2 and 3 only
D1, 2 and 3
Answer [1]

2021 YIJC J2 Prelim P1 Q29

15

Element Y in Period 3 is a metalloid and semiconductor, and its chloride reacts with water to form an acidic solution. Element X has an atomic number one less than Y. What is a property of the oxide of X?

AIt is covalent.
BIt is amphoteric.
CIts formula is XO2.
DIt is a gas at room temperature.
Answer [1]

2023 HCI J2 Prelim P1 Q27

16

M, N and O are in the same period. The oxide of M reacts with water to form a solution of pH less than 7. The oxide of N reacts with water to form a solution that turns damp red litmus blue. The oxide of O dissolves in both hydrochloric acid and aqueous sodium hydroxide. What is the order of increasing proton number?

AM, N, O
BM, O, N
CN, O, M
DO, N, M
Answer [1]

2024 BBSS O Prelim P1 Q20

17

Which statement is not true of the trends of the Group 2 elements and their compounds?

ATheir melting points generally decrease down the group.
BThe reducing power of the elements decreases down the group.
CThey react with water to give solutions that are increasingly alkaline.
DHeating their nitrates and carbonates strongly produces a white solid and an acidic gas.
Answer [1]

2018 NYJC J2 MYE P1-P3 Q17

18

Which property generally increases down Group 2?

Acharge density of the M2+ ion
Belectronegativity
Cmelting point
Dthermal stability of the carbonate
Answer [1]

2021 CJC J2 Prelim P1 Q10

19

The Group 2 metals have higher melting points than the Group 1 metals. Which factors could contribute?

1 There are smaller distances between atoms in the metallic lattices of the Group 2 metals.
2 Two valence electrons from each Group 2 atom are available for bonding in the lattice.
3 The Group 2 metals have the higher first ionisation energy.

A1, 2 and 3
B1 and 2 only
C2 and 3 only
D1 only
Answer [1]

2023 ACJC J2 Prelim P1 Q4

20

Which statement about the Group 17 elements and their compounds is incorrect?

AWhen aqueous sodium chloride is added to aqueous bromine, the orange solution is decolourised.
BWhen aqueous silver nitrate is added to aqueous sodium chloride followed by nitric acid, a white precipitate remains.
CWhen aqueous chlorine is added to excess sodium thiosulfate, followed by barium nitrate, a white precipitate forms.
DWhen chlorine gas is bubbled through potassium iodide, the solution turns brown.
Answer [1]

2022 TJC J2 Prelim P1 Q9

21

X is a Group 1 metal more reactive than sodium. Y and Z are Group 17 elements. X reacts with Y to form a salt. A solution of this salt reacts with Z to form a different salt. What are X, Y and Z?

XYZ
AKCl2I2
BLiCl2Br2
CLiBr2Cl2
DKI2Cl2
Arow A
Brow B
Crow C
Drow D
Answer [1]

2024 Greendale O Prelim P1 Q23

22

Metals Q, R, S and T form cations Q2+, R2+, S+ and T2+. Solid Q placed in a solution of T2+ becomes coated with T. Solid Q does not react with a solution of R2+. Only the carbonate of S does not decompose on heating. T reacts with hydrochloric acid to give hydrogen. What is the order of decreasing reactivity?

AR, Q, T, S
BS, R, Q, T
CS, T, Q, R
DT, Q, R, S
Answer [1]

2024 Zhonghua O Prelim P1 Q28

23

The table shows three metals and how each is extracted.

metalmethod of extraction
Preduction of the ore by carbon
Qelectrolysis
Rmined from the ground as the metal

Which statement is true?

AMetal Q is high up in the reactivity series.
BMetal R is most likely above hydrogen in the reactivity series.
CMetal R is the most reactive of the three metals.
DThe oxide of P is the most stable of the three oxides.
Answer [1]

2024 QTSS O Prelim P1 Q25

24

A warship had its hull plated with copper. After two years at sea, the iron parts in contact with the copper plates were more corroded than normal. What is the best explanation?

ACopper acts as a catalyst to speed up corrosion.
BCopper reacts with the iron to increase corrosion.
CIron displaces copper to form iron(III) oxide.
DIron is more reactive and corrodes in place of copper.
Answer [1]

2024 VS O Prelim P1 Q29

The Periodic Table of Elements, from the A Level Chemistry Data Booklet (8873, 9476, 9813)